有机化学 ›› 1987, Vol. 7 ›› Issue (1): 62-66. 上一篇    下一篇

研究论文

用镧系元素(III)测定有机化合物中的磷和氟

谢正秋   

  1. 武汉大学化学系
  • 发布日期:1987-02-25

Determination of phosphorus and fluorine in organic compounds by using lanthanides

XIE ZHENGQIU   

  • Published:1987-02-25

应用14个镧系元素(III)对有机化合物中的磷和氟进行了测定, 阐明了影响测定的因素. 测定的误差:磷为±0.20%,氟为±0.30%.

关键词: 络合滴定, 氟, 铥, 有机磷化合物, 镧系元素, 磷, 铈, 有机氟化合物, 镧, 同时测定, 钆, 镝, 钐, 铕, 镥, EDTA滴定, 铽, 镨, 铒, 钕, 钬,

P and F contained in organic compounds were determine by using lanthanides after decomposition in an O flask. All lanthanides(III) could be used for determing P by direct titration, of which Dy-Lu lanthanides could prevent the interference of S. P in F-contg. sample could be determine by adding concentrated H2SO4 into the absorption medium and concentrating to remove F-. La-Dy lanthanides were used for determing F. The excess lanthanides were determine by EDTA back-titrn. The percentage of F can be obtained after the amount of P and the total content of P and F were determine The max. error of determing P was ?.20%, and F ?.30%.

Key words: COMPLEXOMETRY, FLUORINE, THULIUM, ORGANO PHOSPHORUS COMPOUNDS, LANTHANON, PHOSPHORUS, CERIUM, ORGANO FLUORINE COMPOUNDS, LANTHANUM, SIMULTANEOUS DETERMINATIONS, GADOLINIUM, DYSPROSIUM, SAMARIUM, EUROPIUM, LUTETIUM, EDTA TITRATION, TERBIUM, PRASEODYMIUM, ERBIUM, NEODYMIUM, HOLMIUM, YTTERBIUM

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