有机化学 ›› 1990, Vol. 10 ›› Issue (3): 258-260. 上一篇    下一篇

研究论文

茄黄斑螟性信息素化学的结构鉴定

孔繁蕾;于生棣;于永庆;胡新华;徐建伟;朱平仇   

  1. 江苏省激素研究所
  • 发布日期:1990-06-25

Sex pheromone of eggplant borer, leucinodes orbonalis gurnee

KONG FANLEI;YU SHENGDI;YU YONGQING;HU XINHUA;XU JIANWEI;ZHU PINGQIU   

  • Published:1990-06-25

本文采用TLC、.GC、微量臭氧化和GC-MS等分析方法, 从茄黄斑螟雌蛾性腺体提取物中, 分离和鉴定出性信息素反-11-十六碳烯醇乙酸酯(1a)。触角电位和田间试验证明, 天然提取物和合成样品均有强烈的生物活性。

关键词: 薄层色谱, 碳烯, 乙酸酯, 田间试验, 十六碳化合物, 臭氧化, 气相色谱, 结构分析, 触角电位, 性信息素

TLC was used to sep. the components of pheromone glands from female eggplant borers, L. orbonalis. Synthetic (E)-11-hexadecenyl acetate had an identical gas chromatog. retention time as the natural pheromone. In the electroantennogram puff test, the male eggplant borers responded stronger to synthetic (E)-11-hexadecenyl acetate than to the Z isomer. In field trapping, more males were captured by traps baited with 300 and 500 mg of the E isomer than with 6 live female specimens. Evidently, (E)-11-hexadecenyl acetate is the main component of eggplant borer sex pheromone.

Key words: ACETIC ACID ESTER, THIN-LAYER CHROMATORGAPHY, C16 COMPOUNDS, CARBENE, FIELD EXPERIMENTS, OZONIZATION, GAS CHROMATOGRAPHY, ELECTROANTENNOGRAM, STRUCTURAL ANALYSIS, SEX PHEROMONE

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