有机化学 ›› 1991, Vol. 11 ›› Issue (2): 174-178. 上一篇    下一篇

研究论文

环状缩醛对某些含官能团烯烃的自由基加成反应

黄乃聚;徐良衡;叶明新;冯   

  1. 复旦大学化学系
  • 发布日期:1991-04-25

The radical addition of cyclic acetals to some alkenes containing functional groups

HUANG NAIJU;XU LIANGHENG;FENG   

  • Published:1991-04-25

本文报道了环状缩醛与某些含官能团烯烃的自由基加成反应。

关键词: 红外分光光度法, 加成反应, 元素分析, 烯烃, 自由基反应, 质子磁共振谱法, 缩醛, 环状化合物

Alkyl esters are prepared by the radical addition of cyclic acetals to functionalized alkenes. Thus, acetal I with maleic anhydride gave 88% adduct II. A possible mechanism was suggested.

Key words: ELEMENTAL ANALYSIS, INFRARED SPECTROPHOTOMETRY, ALKENE, ADDITION REACTION, FREE RADICAL REACTION, PROTON MAGNETIC RESONANCE SPECTROMETRY, ACETAL, CYCLIC COMPOUNDS

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