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有机化学
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有机化学 ›› 1992, Vol. 12 ›› Issue (2): 159-164. 上一篇    下一篇

研究论文

三丁基锡O, O-二芳基二硫代磷酸酯的合成及生物活性的初步研究

谢庆兰;罗宁;李靖;荆煦瑛   

  1. 南开大学元素有机化学研究所
  • 发布日期:1992-04-25

Synthesis of tributyltin O,O-diaryldithiophosphates and preliminary study of their biological activities

XIE QINGLAN;LUO NING;LI JING;JING XUYING   

  • Published:1992-04-25

被引次数

35

本文报道了由三丁基氯化锡和0, 0-二芳基二硫代磷酸钾盐反应合成三丁基锡O,O-二硫代磷酸酯。并经IR, ^1H NMR, ^1^3CNMR, ^1^1^9SN NMR 和MS分析, 生物测定表明这类化合物具有较高的杀菌活性和除草性。

关键词: 生物活性, 硫代磷酸酯, 杀菌剂, 红外分光光度法, 钾化合物, 除草剂, 碳13核磁共振谱法, 质子磁共振谱法, 氧化物, 有机锡化合物

Title compounds Bu3SnSP(S)(OR)2 (R = Ph, 3-ClC6H4, 4-ClC6H4, 2,4-Cl2C6H3, 2-, 3-, 4-MeC6H4, 4-Me3CC6H4, 4-MeOC6H4 2,4-Me2C6H3, 3,4-Me2C6H3, 2,4,5-Cl3C6H2) were prepared in 70.2-81.4% yield by refluxing Bu3SnCl and KSP(S)(OR)2 in acetone for 6 h. Some of the title compounds showed miticidal, fungicidal, or herbicidal activities.

Key words: INFRARED SPECTROPHOTOMETRY, BIOLOGICAL ACTIVITY, BACTERICIDAL AGENTS, C13 NMR SPECTROMETRY, HERBICIDES, POTASSIUM COMPOUNDS, ORGANO TIN COMPOUNDS, PROTON MAGNETIC RESONANCE SPECTROMETRY, OXIDE, THIOPHOSPHATE

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