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有机化学
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有机化学 ›› 1992, Vol. 12 ›› Issue (2): 185-189. 上一篇    下一篇

研究论文

1,7,7-三甲基双环[2.2.1]庚基环烷基(或环取代的烷基)醚的合成

谈樊峰;余金权;陈欣权;周萍;冯爱群;萧树德   

  1. 中国科学院广州化学研究所
  • 发布日期:1992-04-25

Syntheses of 1,7,7-Trimethylbicyclo [2.2.1] heptyl cycloalkyl (or ring-substituted-alkyl) ethers

TAN FANFENG;YU JINQUAN;CHEN XINQUAN;ZHOU PING;ENG AIQUN;XIAO SHUDE   

  • Published:1992-04-25

本文报道以缺铝氢型丝光沸石催化莰烯或三环烯与几种环醇, 如环戊醇、环乙醇、四氢糖醇、苯甲醇、苯乙醇、2-甲基苯乙醇等烷氧基化反应的结果。

关键词: 苯乙醇 P, 环庚烷 P, 质子磁共振谱法, 红外分光光度法, 醚, 苯乙醇, 沸石, 元素分析, 苯甲醇, 环己醇

The direct alkoxylation of camphene and tricyclene with alcs. (cyclopentanol, cyclohexanol, tetrahydrofurfuryl alcohol, benzyl alcohol, phenethyl alcohol, 2-phenylpropanol-1) in the presence of H-Mordenite is studied. These reactions lead to the one-step syntheses of the title compounds and small amount of byproducts 6,7,7-trimethylbicyclo [2.2.1]heptyl alkyl ethers. Hydrogenation of products I (R = PhCH2, phenylethyl, 2-phenylpropyl) affords I (R = cyclohexylmethyl, 2-cyclohexylethyl, 2-cyclohexyl-2-propyl) resp. The relation between odor and structure of the title compounds is also discussed.

Key words: INFRARED SPECTROPHOTOMETRY, PHENYLETHYL ALCOHOL P, PROTON MAGNETIC RESONANCE SPECTROMETRY, ZEOLITE, PHENYLETHYL ALCOHOL, ETHER, CYCLOHEXANOL, ELEMENTAL ANALYSIS, BENZALCOHOL, CYCLOHEPTANE P

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