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有机化学
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有机化学 ›› 1995, Vol. 15 ›› Issue (3): 284-287. 上一篇    下一篇

研究论文

5,6-二亚甲基二环[2.2.1]庚-2-醇的四种立体异构体的合成与构型

邹志琛;宫景渠;李希友   

  1. 山东师范大学化学系
  • 发布日期:1995-06-25

Synthesis and configurations of optically pure stereoisomers of 5,6-dimethylidenebicyclo [2.2.1] heptan-2-ol

ZOU ZHICHEN;GONG JINGQU;LI XIYOU   

  • Published:1995-06-25

本文报道了手性桥环化合物5,6-二亚甲基二环[2.2.1]庚-2-醇的四种光学纯立体异构体的合成及其比旋光度[α]~D, 并通过它们之间的相互关系, 确定了它们的绝对构型.

关键词: 合成, 立体异构, 手性试剂, 绝对构型, 桥环化合物

Four optically pure stereoisomers of 5,6- dimethylidenebicyclo [2.2.1] hepten-2-ol were prepared. The absolute configurations of these stereoisomers were determined by [α]~D comparison with the configurationally well-established (+)-(1R, 2S, 4R)-dimethylidenebicyclo [2.2.1] hepten-2-ol .

Key words: SYNTHESIS, STEREOISOMERISM, BRIDGE COMPOUNDS, CHIRAL REAGENT, ABSOLUTE CONFIGURATION

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