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有机化学
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有机化学 ›› 1995, Vol. 15 ›› Issue (4): 408-410. 上一篇    下一篇

研究论文

1,4-二硝基-2,3-二硝胺基哌嗪的合成

陆明;魏运洋;吕春绪   

  1. 南京理工大学化工学院
  • 发布日期:1995-08-25

Synthesis of 1,4-dinitro-2,3-dinitraminepiperazine

LU MING;WEI YUNYANG;LU CHUNXU   

  • Published:1995-08-25

本文以乙二胺, 乙二醛和脲为原料, 通过Mannich反应, 合成出2,5,7,9-四氮杂双环[4.3.0]壬-8-酮盐酸盐(1); 化合物1 亚硝化给出2,5-二亚硝基-2,5,7,9-四氮杂双环[4.3.0]壬-8-酮(2); 硝化化合物2制得2,5,7,9-四硝基-2,5,7,9-四氮杂双环[4.3.0]壬-8-酮(3); 化合物3水解制得1,4-二硝基-2,3-二硝胺基哌嗪(4).

关键词: 合成, 哌嗪, 硝胺类炸药

The synthesis of 2,5,7,9-tetrazabicyclo [4.3.0] nonan- 8-one hydrochloride (1) from ethylenediamine, glyoxal and urea by Mannich reaction was reported. Nitrosation of compound 1 gave 2,5-dinitroso-2,5,7,9-tetrazabicyclo [4.3.0] nonan-8-one (2). Nitration of compound 2 gave 2,5,7,9- tetranitro-2,5,7,9-tetrazabicyclo [4.3.0] nonan-8-one (3). 1,4-Dinitro-2,3-dinitraminepiperazine (4) was synthetized by hydrolysis of compound 3.

Key words: SYNTHESIS, PIPERAZINE, NITRO-AMINE COMPOUND EXPLOSIVES

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