有机化学 ›› 1995, Vol. 15 ›› Issue (4): 429-432. 上一篇    下一篇

研究论文

苄基醚选择性间接电氧化的研究

于伯章;李毅;丁正谊;李青;王桂兰;李志鸿;蔡昆   

  1. 新乡师范专科学校化学系;河南师范大学化学系2
  • 发布日期:1995-08-25

Studies on the selective indirect electrooxidation of benzyl ethers

YU BOZHANG;LI YI;DING ZHENGYI;LI QING;WANG GUILAN;LI ZHIHONG;CAI KUN   

  • Published:1995-08-25

以Mn(Ⅲ) / Mn(Ⅱ)为 间接氧化还原体系研究苄基醚的氧化. 实验结果表明该体系能高产率选择性地氧化苄基醚为 苯甲醛和相应的醇. 阳极液中Mn(Ⅱ)可以循环使用.

关键词: 槽外法, 醚, 苄基, 选择氧化, 河南省基础研究基金, 间接法, 电氧化

Indirect electrooxidation of benzyl ethers was studied using Mn(Ⅲ) / Mn(Ⅱ) as a redox system . The experimental results showed that this system affords better selectivity and yield for oxidation of benzyl ethers to the corresponding benzaldehyde and alcohlos. Mn(Ⅱ) in the anolyte may be recycled.

Key words: ETHER, BENZYL GROUP, SELECTIVE OXIDATION, INDIRECT METHOD, ELECTROOXIDATION

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