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有机化学
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有机化学 ›› 1995, Vol. 15 ›› Issue (6): 622-626. 上一篇    下一篇

研究论文

聚苯乙烯-二苯基膦-铜(Ⅰ)-四氢化硼络合物的制备及其对酰氯的还原

熊桂荣;黄锦霞;张万轩;陈家威   

  1. 武汉市乡镇企业管理局科技处;湖北大学化学系
  • 发布日期:1995-12-25

Preparation of polystyryl diphenyl phosphine copper(Ⅰ) tetrahydroborate and reduction of acyl chloride

XIONG GUIRONG;HUANG JINXIA;ZHANG WANXUAN;CHEN JIAWEI   

  • Published:1995-12-25

被引次数

13

以不同交联度(1%, 2%, 4%, 7%, 8%, 12%)的聚苯乙烯树脂为支载体, 制备了聚苯乙烯-二苯基膦-铜-四氢化硼络合物, 对它们的容量和结构进行了测试和分析, 并研究了该络合物在不同温度、溶剂、催化剂下, 对苯甲酰氯, 肉桂酰氯, 对硝基苯甲酰氯的还原性能以及其回收再生后的重复使用情况。

关键词: 四氢化硼, 二苯基膦, 红外分光光度法, 高速液体色谱, 还原剂, 铜络合物, 聚苯乙烯, 酰氯

A few polystyryl diphenyl copper(Ⅰ) Tetrahydroborate complexes (PDPCT) were prepared using various crosslinking (1%, 2%, 4%, 7%, 8%, 12%) polystyrene beads as supports. Their contents and structures were tested and analyzed, which their behavior reducing benzoyl chlo-ride, cinnamoyl chloride, p-nitrobenzoyl chloride to the corresponding aldehydes or alcohols in the different conditions of temperature, solvent and catalyst and recovering were studied.

Key words: INFRARED SPECTROPHOTOMETRY, HIGH SPEED LIQUID CHROMATOGRAPHY, DIPHENYLPHOSPHINE, POLYSTYRENE, COPPER COMPLEX, REDUCER, ACYL CHLORIDES

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