有机化学 ›› 1998, Vol. 18 ›› Issue (5): 425-431. 上一篇    下一篇

研究论文

血卟啉醚类化合物的裂解反应及乙烯基烷氧乙基 次卟啉类化合物的合成

张广明;计国桢;胡蕙   

  1. 中国科学院上海有机化学研究所.上海(200032);复旦大学化学系.上海(200433)
  • 发布日期:1998-10-25

Pyrolytic degradation of hematoporphrin Ⅸ ethers and synthesis of vinyl ether porphrin compounds

Zhang Anming;Ji Guozhen;Hu Hui   

  1. Shanghai Inst Organ Chem., CAS.Shanghai(200032);Fudan Univ, Dept Chem.Shanghai(200433)
  • Published:1998-10-25

本文考察了3,8-二溴乙基次卟啉Ⅸ与醇(酚)、水的反应产物及血卟啉单、双醚的合成方法,研究了血卟啉醚类的裂解反应,合成了一系列乙烯基烷氧乙基次卟啉类化合物。

关键词: 卟啉, 乙烯基化合物, 表征, 裂解反应, 合成, 烷氧络合物, 血卟啉,

The reactions of 3, 8-dibromoethyl deuteroporphrin Ⅸ with alcohol (phenol) or the mixture of alcohols and water were studied. Vinyl ether deuteroporphrin Ⅸ were synthesized from the corresponding hematoporphrin Ⅸ mono- and diethers by pyrolytic degradation.

Key words: CHARACTERIZATION, ETHER, CRACKING REACTION, ALKOXY COMPLEX, SYNTHESIS, PORPHYRIN, VINYL COMPOUNDS, HEMATOPORPHYRIN

中图分类号: