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有机化学
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有机化学 ›› 1998, Vol. 18 ›› Issue (5): 447-451. 上一篇    下一篇

研究论文

Ph~2C(OH)CH=CHSnAr~3的卤化物的合成、表征和性质

朱东升;戴慧聪;单希林;傅芳信;潘华德   

  1. 东北师范大学化学系.长春(130024);大庆石油学院化工系
  • 发布日期:1998-10-25

Synthesis, properties and structure of the halides of (Z)-3- triarylstannyl-1, 1-diphenyl-2-propenyl-1-ol

Zhu Dongsheng;Dai Huicong;Shan Xilin;Fu Fangxin;Pan Huade   

  1. NE Normal Univ, Dept Chem.Changchun(130024)
  • Published:1998-10-25

首次以非碳环醇(Z)-3-三芳基锡基-1,1-二苯基-2-丙烯基-1-醇[Ph~2C(OH)CH=CHSnAr~3]和卤素或拟卤素发生取代反应得到卤化物,并以此合成了氢氧化物、氧化物和配合物。通过元素分析、IR和^1HNMR等对上述17种新化合物的结构进行了表征,并提出了卤化物的性质。

关键词: 锡络合物, 卤络合物, 结构表征, 金属卤化物, 卤素, 合成, 丙烯醇P, 有机锡化合物

The reaction of the compound (Z)-3-triarylstannyl-1, 1-diphenyl- 2- propenyl-1-ol with ICl, Br~2, I~2 formed organotin halides, which reacted with KOH to form organotin oxide or hydroxide. The complexes were obtained by the organotin halides with three ligandrs (2, 2'- bipyridyl, 1, 10-phenanthroline, 8-hydroxyquinoline). The seventeen new compounds were characterized by means of elemental analysis, IR and ^1H NMR. Studied on the properties of the halides.

Key words: STRUCTURE CHARACTERISTICS, TIN COMPLEX, HALOGEN, PROPENOL P, SYNTHESIS, HALOGEN COMPLEX, METAL HALIDE, ORGANO TIN COMPOUNDS

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