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有机化学
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有机化学 ›› 1999, Vol. 19 ›› Issue (3): 249-254. 上一篇    下一篇

研究论文

钴萘酞菁的合成

王小兵;唐代华;王凤奇;甄珍;张建成;刘新厚   

  1. 中国科学院感光化学研究所.北京(100101)
  • 发布日期:1999-06-25

Synthesis of naphthalocyaninatocobalt compounds

Wang Xiaobing;Tang Daihua;Wang Fengqi;Zhen Zhen;Zhang Jiancheng;Liu Xinhou   

  1. Inst Photog Chem, Acad Sinica.Beijing(100101)
  • Published:1999-06-25

被引次数

13 | 2

采用Diels-Alder方法合成了2,3-萘二腈和6,7-二溴-2,3-萘二腈化合物,并以此为前体成功地合成了相应的钴萘酞菁系列化合物---一种新型的功能有机材料。另外还探讨了酞菁形成的机理,并讨论了若干影响因素。这些化合物具有较好的稳定性,在胺类或其它含氮的有机溶剂中有较好的溶解度,如苯胺、二甲基甲酰胺(DMF)或吡啶等。

关键词: 机理, 合成, 钴萘酞菁, 萘二腈, 有机材料, 无机材料

2, 3-Naphthalocyaninatocobalt compounds, a new type of functional materials, have been successfully prepared by using of Diels-Alder reaction. The mechanism of the synthetic reactions and the factors which have influence on reaction are discussed. Despite their insolubility in many organic solvents, they are found to be soluble in nitrogen-containing solvents, such as DMF and pyridine.

Key words: INORGANIC MATERIALS, SYNTHESIS, MECHANISM

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