有机化学 ›› 2000, Vol. 20 ›› Issue (2): 155-167. 上一篇    下一篇

研究论文

环辛四烯基稀土金属有机配合物

张立新;周锡庚;蔡祖芳;黄祖恩   

  1. 复旦大学化学系.上海(200433)
  • 发布日期:2000-04-25

Cyclocctatetraehyl organolanthanide complexes

Zhang Lixin;Zhou Xigeng;Cai Zufang;Huang Zuen   

  1. Fudan Univ, Dept Chem.Shanghai(200433)
  • Published:2000-04-25

环辛四烯基稀土配合物是继茂基配合物之后的又一类非常重要的稀土金属有机配合物,本文将就这一领域的发展情况作一个简要的总结和回顾。

关键词: 环辛四烯P, 稀土金属络合物, 结构, 合成

The chemistry of cyclooctatetraenyl lanthanide complexes is currently receiving considerable attention. Many cyclooctatetraenyllanthanide complexes have been reported during the past several decades. The results show that cyclooctatetraenyl ligands with larger size and higher negative charges can often generate stable organolanthanide complexes of novel structures and unique properties. Herein is a brief revview on the synthesis, structure and reactivity of these complexes.

Key words: CYCLOOCTATETRAENE P, RARE EARTH METAL COMPLEX, STRUCTURE, SYNTHESIS

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