有机化学 ›› 2001, Vol. 21 ›› Issue (6): 413-419. 上一篇    下一篇

研究论文

新型高效催化剂: 甲基三氧化铼(MTO)的研究进展

任译;吴云东;田安民   

  1. 四川大学化学学院;香港科技大学化学系
  • 发布日期:2001-06-25

Progress in research on highly efficient novel catalyst: Methyltrioxorhenium (MTO)

Ren Yi;Wu Yundong;Tian Anmin   

  • Published:2001-06-25

甲基三氧化铼(Methyltrioxorhenium,简称MTO)是近十几年来涌现出来的一种高效过渡金属有机催化剂。本文详细介绍了MTO的物理,化学性质,系统地总结了近年来MTO对各类有机反应的催化作用以及催化机理的理论和实验研究。并对未来MTO催化反应的研究作了展望。

关键词: 甲基三氧化铼, 催化剂, 反应机理, 催化反应

Methyltrioxorhenium (MTO), a high-oxidation-state transition metal complex, has been found to be a highly efficient catalyst in the last decade. The physical and chemical properties, the wide application to catalysis of a range of organic reactions, and theoretic as well is experimental researches on the catalytic methanism of MTO are reviewed. Close attention has also been paid to the prospects of the work on MTO's catalyied reaction.

Key words: CATALYST, REACTION MECHANISM, CATALYTIC REACTION

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