有机化学 ›› 2001, Vol. 21 ›› Issue (8): 603-605. 上一篇    下一篇

研究论文

中位-四-(对十六酰氧基苯基)卟啉及其锌配合物的合成、 表征与液晶性

安庆大;杨大智;师同顺;沈红春   

  1. 大连理工大学材料科学与工程系;大连轻工业学院化学工程系;吉林大学化学系 .长春(130023)
  • 发布日期:2001-08-25

Synthesis and characterization of meso-tetra-(4-Palmitoyloxyphenyl) Porphyrin and its zinc complex

An Qingda;Yang Dazhi;Shi Tongshun;Shen Hongchun   

  1. Jilin Univ, Dept Chem.Changchun(130023)
  • Published:2001-08-25

首次合成出中位-四-(对十六酰氧基苯基)卟啉(TPPPH2)及其锌配合物(简称TPPPZn),研究了其液晶性质,结果表明这种卟啉及其锌配合物具有液晶性质。

关键词: 酰氧基, 卟啉, 锌络合物, 合成法, 结构表征, 液晶

The meso-tetra-(4-palmitoyloxyphenyl)porphyrin(TPPPH2) and zinc complex(TPPPZn) were synthesized and characterized by means of molar conduction, elemental analysis, and UV- visible, infrared photoacoustic as well as 1^H NMR spectroscopy. The physical behavior of TPPPH2 and TPPPZn was determined by differential scanning calorimetric(DSC). The results show that TPPPZn exhibit liquid crystal behaviors.

Key words: ACYLOXY, PORPHYRIN, ZINC COMPLEX, SYNTHESIS METHODS, STRUCTURE CHARACTERISTICS, LIQUID CRYSTAL

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