有机化学 ›› 2003, Vol. 23 ›› Issue (8): 776-783. 上一篇    下一篇

研究论文

硝基化合物的不对称迈克尔加成反应

段新方   

  1. 北京师范大学化学系
  • 发布日期:2003-08-25

Asymmetric Michael Additions of Nitro Compounds

Duan Xinfang   

  1. Department of Chemistry, Beijing Normal University
  • Published:2003-08-25

从以下三方面对硝基化合物的不对称迈克尔加成反应进行了较为详细的综述: (1)手性催化剂催化的迈克尔加成,(2)共轭硝基物与手性亲核试剂的迈克加成 ,(3)脂肪族硝基物对手性迈克加成受体的迈克尔加成。

关键词: 硝基化合物, 不对称合成, 迈克尔加成反应

Asymmetric Michael additions of nitro compounds are of remarkable importance in organic asymmetric synthesis due to their easy versatility of transformations. This paper reviews the recent advances of these reactions, which witnesses their extensive utilization in the syntheses of many important optically active compounds.

Key words: NITRO COMPOUNDS, ASYMMETRICAL SYNTHESIS, MICHAEL ADDITION REACTION

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