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有机化学
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有机化学 ›› 2004, Vol. 24 ›› Issue (3): 297-299. 上一篇    下一篇

研究论文

双核锌(II)大杂环配合物的超声催化合成和结构表征

李良学*,a, 刘继德a, 吴爱斌a, 秦少雄a, 李琴a, 邓立志b, 黄筱玲b   

  1. a 湖北长江大学化学系 荆州 434104
    b 武汉大学化学与分子科学学院 武汉 430072
  • 收稿日期:2003-05-06 修回日期:2003-09-10 接受日期:2003-10-08 发布日期:2022-09-20
  • 基金资助:
    国家自然科学基金(No. 20172067)资助项目

Synthesis under Ultrasonic Catalysis and Structural Characterization Dinuclearof Zn(II)-Macroheterocyclic Complex

LI, Liang-Xue*,a, LIU, Ji-Dea, WU, Ai-Bina, QIN, Shao-Xionga, LI, Qina, DENG, Li-Zhib, HUANG, Xiao-Lingb   

  1. a Department of Chemistry, Yangtze University, Jingzhou 434104
    b Department of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072
  • Received:2003-05-06 Revised:2003-09-10 Accepted:2003-10-08 Published:2022-09-20
  • Contact: *E-mail: zhaoguo@mail.sioc.ac.cn

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用超声辐射催化方法,合成了C23H19N2SF3O2Zn(1)-Zn(2)C8H5SF3O2双核锌大杂环配合物,经IR, 1H NMR, 13C NMR, MS和元素分析表征.通过波谱分析表明,Zn(1)采取dsp3杂化与1,2-二氮-5,8-二氧-3,4,10,11-双(苯并)环十四-13-三氟甲基-1-噻吩配位,Zn(2)采取sp2杂化与1′-噻吩-3′-三氟甲基-1′,3′-二丙酮配位,形成双核锌(II)树状型配合物.

关键词: 双核锌(II)配合物, 大杂环, 超声催化, 合成, 结构表征

By ultrasonic catalysis a macroheterocyclic dinuclear complex of C23H19N2SF3O2Zn(1)-Zn(2)C8H5SF3O2 was synthesized. The title compound was characterized by IR, 1H NMR, 13C NMR, MS and elemental analysis. It was found that both Zn(1) complexing to1,5-diazo-8,12-dioxa-4-trifluoromethyl-2-(2-thiophenyl)-6,7,13,14-bibenzocyclotetradecane with dsp3 hybrid orbitals and Zn(2) complexing to2-(1,1,1-trifluoroaceyl) acetylthiophene with sp2 hybrid orbitals produce atree-like dinuclear complex of Zn(II).

Key words: dinuclear Zn(II) complex, macroheterocyclic, ultrasonic catalysis, synthesis, structural characterization