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有机化学
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有机化学 ›› 2004, Vol. 24 ›› Issue (3): 319-321. 上一篇    下一篇

研究简报

钨化合物催化过氧化氢氧化环己酮合成己二酸

丁宗彪, 连慧, 王全瑞, 陶凤岗*   

  1. 复旦大学化学系 上海 200433
  • 收稿日期:2003-03-04 修回日期:2003-09-16 接受日期:2003-09-16 发布日期:2022-09-20
  • 基金资助:
    国家自然科学基金(No. 29974018)资助项目

Oxidation of Cyclohexanone to Adipic Acid with 30% H2O2 and Tungstate Catalyst

DING, Zong-Biao, LIAN, Hui, WANG, Quan-Rui, TAO, Feng-Gang*   

  1. Department of Chemistry, Fudan University, Shanghai 200433
  • Received:2003-03-04 Revised:2003-09-16 Accepted:2003-09-16 Published:2022-09-20
  • Contact: *E-mail: szgaoy@163.net

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在无相转移催化剂的条件下,用Na2WO4·2H2O 或 H7[P(W2O7)6]·xH2O为催化剂,30% H2O2可以将环己酮高产率地氧化成己二酸.钨催化剂用量、反应液酸度对反应结果有着重要的影响.当钨原子与环己酮的摩尔比为1.5%,反应初始液的pH值为1.0时,己二酸的得率可达82%;而且催化体系具有很好的可循环性.

关键词: 环己酮, 钨酸钠, 磷钨酸, 双氧水

Cyclohexanone can be directly oxidized to adipic acid with 30% H2O2 using Na2WO4·2H2O or H7[P-(W2O7)6]·xH2O as a catalyst without any phase transfer catalyst. The quantity of tungstate catalysts and the acidity of reaction mixture affect the results greatly. It is found that when pH ofthe reaction mixture is 1.0 and 1.5% tungstate catalyst is used, 82% yield ofadipic acid can be obtained. The catalyst can be recycled easily with no loss ofthe activity.

Key words: cyclohexanone, sodium tungstate, phosphotungstic acid, peroxide hydrogen