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有机化学
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有机化学 ›› 2004, Vol. 24 ›› Issue (7): 775-777. 上一篇    下一篇

研究论文

3,3-二硝基氮杂环丁烷和 1,1′-亚甲基-双(3,3-二硝基-1-氮杂环丁烷)的合成研究

李洪珍a, 舒远杰*,a, 黄奕刚a, 刘世俊a, 蒋青b   

  1. a中国工程物理研究院化工材料研究所 绵阳 621900
    b四川大学化学学院 成都 610064
  • 收稿日期:2003-09-04 修回日期:2003-12-15 接受日期:2004-01-31 发布日期:2022-09-20
  • 通讯作者: *E-mail: syjfree@sina.com
  • 基金资助:
    中国工程物理研究院基金(No. 20020539)资助项目

Studt on the Synthesis of 3,3-Dinitroazetidine and 1,1′-Bis-(3,3-dinitro- azetidin-1-yl)methane

LI, Hong-Zhena, SHU, Yuan-Jie*,a, HUANG, Yi-Ganga, LIU, Shi-Juna, JIANG, Qingb   

  1. a Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang 621900
    b Faculty of Chemistry, Sichuan University, Chengdu 610064
  • Received:2003-09-04 Revised:2003-12-15 Accepted:2004-01-31 Published:2022-09-20

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3,3-二硝基氮杂环丁烷(DNAZ)的含能盐及衍生物是一类重要的高能量密度材料,因此DNAZ的合成和应用受到了密切关注.采用新的合成方法,以1-叔丁基-3,3-二硝基氮杂环丁烷为起始原料,以76.3%的总收率得到了DNAZ,然后以DNAZ为原料,与多聚甲醛反应,得到了1,1′-亚甲基-双(3,3-二硝基-1-氮杂环丁烷)(DNAZ-CH2-DNAZ).用红外和核磁共振光谱等对各化合物的结构进行了表征.

关键词: 合成, 高能量密度材料, 3,3-二硝基氮杂环丁烷, 1,1′-亚甲基-双(3,3-二硝基-1-氮杂环丁烷)

Because the energetic salts and derivatives of 3,3-dinitroazetidine (DNAZ) area new kind of important high density energetic materials, the synthesis and applications of DNAZ have attracted much attention. In this paper DNAZ was synthesized in 76.3% overall yield starting from 1-tert-butyl-3,3-dinitro-azetidine. In addition, DNAZ reacted with paraformaldehyde giving 1,1′-bis-(3,3-dinitro-azetidin-1-yl)methane (DNAZ-CH2-DNAZ). The structures of these compounds were confirmed by IR, 1H NMR and 13C NMR spectra.

Key words: synthesis, high energy density material, DNAZ, DNAZ-CH2-DNAZ