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有机化学
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有机化学 ›› 2005, Vol. 25 ›› Issue (05): 540-544. 上一篇    下一篇

研究论文

新型尾式硫代苯并噻唑基卟啉化合物的合成与表征

刘新刚，冯亚青*，高博，周立山   

  1. (天津大学化工学院 天津 300072)
  • 收稿日期:2004-03-22 修回日期:2004-11-14 发布日期:2004-04-30
  • 通讯作者: 冯亚青

Synthesis and Characterization of Novel 2-Thiobenzo[d]thiazole Tailed-porphyrin

LIU Xin-Gang,FENG Ya-Qing*,GAO Bo,ZHOU Li-Shan   

  1. (School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072)
  • Received:2004-03-22 Revised:2004-11-14 Published:2004-04-30
  • Contact: FENG Ya-Qing

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578

被引次数

9

通过不对称的单羟基卟啉化合物、溴代烷烃和巯基苯并噻唑合成了一系列新型硫代苯并噻唑基尾式卟啉化合物, 并采用核磁共振氢谱、碳谱、红外光谱、质谱和元素分析对卟啉化合物的结构进行了表征.

关键词: 尾式卟啉, 巯基苯并噻唑, 合成, 表征

A series of new 2-thiobenzo[d]thiazole-linked tailed porphyrins were synthesized by the un-symmetrical monohydroxyporphyrins with alkyl bromides followed by treatment with 2-thiobenzo- [d]thiazole. And their structures were confirmed by IR, 1H NMR, 13C NMR, MS spectra and elemental analysis.

Key words: 2-thiobenzo[d]thiazole, tailed porphyrin, synthesis, structure identification