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有机化学
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有机化学 ›› 2005, Vol. 25 ›› Issue (11): 1446-1449. 上一篇    下一篇

研究简报

KF/Al2O3催化下4-芳基-9,10-二氢萘并[2,1-b]-4H-吡喃衍生物的合成

李玉玲1,2，王香善*,1,2，曾兆森1，娄秀莲1
史达清1,2，屠树江1,2   

  1. (1徐州师范大学化学系 徐州 221116)
    (2江苏省药用植物生物技术重点实验室 徐州 221116)
  • 收稿日期:2005-04-12 修回日期:2005-05-13 发布日期:2005-10-30
  • 通讯作者: 王香善

Synthesis of 4-Aryl-9,10-dihydronaphtho[2,1-b]-4H-pyran Deriva-tives Catalyzed by KF/Al2O3

LI Yu-Ling1,2,WANG Xiang-Shan*,1,2,ZENG Zhao-Sen1,LOU Xiu-Lian1
SHI Da-Qing1,2,TU Shu-Jiang1,2   

  1. (1 Department of Chemistry, Xuzhou Normal University, Xuzhou 221116)
    (2 The Key Laboratory of Biotechnology on Medical Plant of Jiangsu Province, Xuzhou 221116)
  • Received:2005-04-12 Revised:2005-05-13 Published:2005-10-30
  • Contact: WANG Xiang-Shan

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在KF/Al2O3催化下, α,β-不饱和腈或α,β-不饱和羧酸酯和7-甲氧基-1,2,3,4-四氢-2-萘酮反应, 生成了一系列4-芳基-9,10-二氢萘并[2,1-b]-4H-吡喃衍生物. 产物的结构通过红外光谱和核磁共振氢谱进行表征, 并通过X单晶衍射分析进一步证实产物的结构.

关键词: KF/Al2O3, 萘并吡喃, 合成

4-Aryl-9,10-dihydronaphtho[2,1-b]-4H-pyran derivatives have been synthesized by the reaction of α,-unsaturated nitriles or α,-unsaturated carboxylate with 7-methoxy-1,2,3,4-tetrahydronaphtha- len-2-one catalyzed by KF/Al2O3. The structures of products were characterized by IR and 1H NMR spectra, and further confirmed by X-ray analysis.

Key words: synthesis, naphthopyran, KF/Al2O3