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有机化学
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有机化学 ›› 2006, Vol. 26 ›› Issue (02): 233-235. 上一篇    下一篇

研究简报

α-氨基膦酸酯衍生物的合成及其表征

廖新成*,1，刘伦1，郭艳春1，曹书霞1，荣垂林1，赵玉芬1,2   

  1. (1郑州大学化学系 河南省化学生物与有机化学重点实验室 郑州 450052)
    (2清华大学生命有机膦及化学生物学教育部重点实验室 北京 100084)
  • 收稿日期:2005-05-25 修回日期:2005-08-15 发布日期:2006-01-21
  • 通讯作者: 廖新成

Synthesis and Character of α-Aminophosphonate Derivatives

LIAO Xin-Cheng*,1,LIU Lun1,GUO Yan-Chun1,CAO Shu-Xia1
RONG Chui-Lin1, ZHAO Yu-Fen1,2   

  1. (1 Key Laboratory of Chemical Biology and Organic Chemistry, Zhengzhou University, Zhengzhou 450052)
    (2 Key Laboratory for Bioorganic Phosphorus Chemistry and Chemical Biology, Ministry of Education of China,
    Tsinghua University, Beijing 100084)
  • Received:2005-05-25 Revised:2005-08-15 Published:2006-01-21
  • Contact: LIAO Xin-Cheng

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合成了一系列N端含有均三唑并噻二唑的α-氨基膦酸酯衍生物, 其结构经过红外、核磁共振氢谱、磷谱、质谱和高分辨质谱等确证.

关键词: 均三唑并噻二唑, 氨基膦酸酯, 合成

A series of N-(m-s-triazolo[2,1,-b]-1',3',4'-thiadiazol-2-yl)phenyl-α-aminophosphonates were synthesized. The structures of these compounds were confirmed by IR, 1H NMR, 31P NMR, MS and HRMS spectra. The two alkoxyl groups linked to phosphorus atom show unequivalent behavior in 1H NMR.

Key words: α-aminophosphonate, synthesis, s-triazolo[2,1,-b]-1',3',4'-thiadiazole