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有机化学
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有机化学 ›› 2006, Vol. 26 ›› Issue (04): 551-555. 上一篇    下一篇

研究简报

取代1,1'-联-2-萘酚在铜胺络合物催化作用下的氧化反应

王秀珍，陈泳，汪波，庞冀燕，许遵乐*   

  1. (中山大学化学与化学工程学院 广州 510275)
  • 收稿日期:2005-07-12 修回日期:2005-10-28 发布日期:2006-03-31
  • 通讯作者: 许遵乐

Catalytic Oxidation Reaction of Substituted 1,1′-Bi-2-naphthols with Copper-Amine Complex

WANG Xiu-Zhen,CHEN Yong,WANG Bo,PANG Ji-Yan,XU Zun-Le*   

  1. (School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou 510275)
  • Received:2005-07-12 Revised:2005-10-28 Published:2006-03-31
  • Contact: XU Zun-Le

PDF

1290

被引次数

16

用CuCl2•2H2O与小分子的有机胺形成络合物, 模拟氧化还原酶对多米诺式反应(Domino reaction)进行催化反应, 在氧气存在条件下, 取代1,1'-联-2-萘酚化合物被氧化为二苯并呫吨类化合物, 产物的结构经核磁共振、红外光谱及质谱进行确证.

关键词: 铜胺络合物, 合成, 取代联萘酚, 二苯并呫吨, 多米诺式反应

The complex of CuCl2•2H2O with small molecular amine as a catalyst for Domino reaction, which was a mimic to oxidoreductase, was reported. Substituted 1,1'-bi-2-naphthols were oxidized into dibenzoxanthenoids in the presence of O2. The structures of these compounds were characterized with 1H NMR, IR and FAB-MS spectra.

Key words: substituted 1,1'-bi-2-naphthol, synthesis, dibenzoxanthenoid, Domino reaction, >copper-amine complex