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有机化学
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有机化学 ›› 2006, Vol. 26 ›› Issue (08): 1079-1082. 上一篇    下一篇

研究论文

微波辅助合成双1,2,4-三嗪化合物及其荧光特性研究

孙一峰*,1，潘文龙2，吴仁涛1，宋化灿2   

  1. (1泰山学院化学系 泰安 271021)
    (2中山大学化学与化学工程学院 广州 510275)
  • 收稿日期:2005-08-25 修回日期:2006-02-20 发布日期:2006-07-26
  • 通讯作者: 孙一峰

Microwave-Assisted Synthesis and Fluorescence Characterization of Bis-1,2,4-triazine Derivatives

SUN Yi-Feng*,1,PAN Wen-Long2,WU Ren-Tao1,SONG Hua-Can2   

  1. (1 Department of Chemistry, Taishan University, Taian 271021)
    (2 School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275)
  • Received:2005-08-25 Revised:2006-02-20 Published:2006-07-26
  • Contact: SUN Yi-Feng

PDF

1025

被引次数

15

以联苯甲酰、二甲酰肼为原料, 采用微波技术合成了5个双1,2,4-三嗪化合物3, 产率72%～85%, 利用元素分析、MS, IR, 1H NMR和荧光光谱对其结构进行了表征, 并研究了金属离子对化合物3a的荧光性质的影响. 结果表明, 微波合成具有缩短反应时间、提高产率的优点; Cu2＋, Ni2＋等金属离子对化合物3a产生明显的荧光猝灭作用.

关键词: 荧光性质, 荧光猝灭, 离子识别, 1,2,4-三嗪, 微波合成

Five bis-1,2,4-triazine derivatives were synthesized by the reaction of benzil, dihydrazide and ammonium acetate in acetic acid under microwave irradiation with yields of 72%～85%. The structures of the title compounds were characterized by elemental analysis, IR, 1H NMR, MS and fluorescence spectra. The effect of metal ions on fluorescence characterization of compound 3a was investigated. The microwave irradiation dramatically shortened the reaction times, affording the desired products in high yields. The selective interaction between metal ions (Cu2＋, Ni2＋) and 3a led to obvious fluorescence quenching.

Key words: fluorescence characterization, fluorescence quenching, microwave-assisted synthesis, ion recognition, 1,2,4-triazine