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有机化学
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有机化学 ›› 2006, Vol. 26 ›› Issue (08): 1087-1092. 上一篇    下一篇

研究论文

卟啉-salen化合物的合成及谱学性质研究

赵小菁*,1，阮文娟2，朱志昂2，金黎明1，范圣第1   

  1. (1大连民族学院生物工程系 大连 116600)
    (2南开大学化学系 天津 300071)
  • 收稿日期:2005-09-20 修回日期:2006-02-28 发布日期:2006-07-26
  • 通讯作者: 赵小菁

Study on Synthesis and Spectral Properties of Porphyrin-salen Compounds

ZHAO Xiao-Jing*,1,RUAN Wen-Juan2,ZHU Zhi-Ang2
JIN Li-Ming1,FAN Sheng-Di1   

  1. (1 Department of Biochemical Engineering, Dalian Nationalities University, Dalian 116600)
    (2 Department of Chemistry, Nankai University, Tianjin 300071)
  • Received:2005-09-20 Revised:2006-02-28 Published:2006-07-26
  • Contact: ZHAO Xiao-Jing

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1378

被引次数

17

合成了三种含羟基的salen化合物: salen-OH, Cl-salen-OH和t-Bu-salen-OH, 并用后两种羟基salen与5,10,15-三苯基-20-对羟基苯基卟啉(HPTPP)以烷烃链[O(CH)6O及O(CH)10O]相连合成四种卟啉-salen化合物: HPSC6 (1), HPSC10 (2), HPt-BuSC6 (3), HPt-BuSC10 (4)及其金属锌(II)化合物: ZnPSC6 (Zn-1), ZnPSC10 (Zn-2), ZnPt-BuSC6 (Zn-3), ZnPt-BuSC10 (Zn-4). 用元素分析、核磁共振、红外光谱、紫外-可见光谱等手段对其组成的结构进行表征, 并对其谱学性质进行了研究.

关键词: 卟啉-salen化合物, 合成, 光谱性质

Three salen compounds: salen-OH, Cl-salen-OH and t-Bu-salen-OH with hydroxyl group were synthesized. By salen-OH and t-Bu-salen-OH with 5,10,15-triphenyl-20-mesohydroxylphenylporphyrin (HPTPP) as a starting material, respectively, a series of novel porphyrin-salen compounds: HPC6S (1), HPC10S (2), HPC6S' (3) and HPC10S' (4) and their corresponding zinc(II) porphyrin-salen complexes: ZnPC6S (Zn-1), ZnPC10S (Zn-2), ZnPC6S' (Zn-3), ZnPC10S' (Zn-4) were synthesized and char-acterized by elemental analysis, FTIR, 1H NMR and UV-Vis spectra, where P denotes porphy-rin, S means salen and S' indicates t-Bu-salen.

Key words: synthesis, spectral property, porphyrin-salen compound