有机化学 ›› 2007, Vol. 27 ›› Issue (08): 946-957. 上一篇    下一篇

综述与进展

三苯三戊并烯及其衍生物的合成研究进展

张陶香a,周岭a,曹小平*,a,KUCK, Dietmar*,b   

  1. (a兰州大学化学化工学院 功能有机分子化学国家重点实验室 兰州 730000)
    (b Department of Chemistry, Bielefeld University, Universitätsstraβe 25, D-33615 Bielefeld, Germany)
  • 收稿日期:2006-09-06 修回日期:1900-01-01 发布日期:2007-07-30
  • 通讯作者: 曹小平*

Progress in Synthesis of Tribenzotriquinacene and Its Derivatives

ZHANG Tao-Xianga, ZHOU Linga, CAO Xiao­Ping*,a, KUCK Dietmar*,b   

  1. (a State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engi-neering,
    Lanzhou University, Lanzhou 730000)
    (b Department of Chem-istry, Bielefeld University, Universitätsstraβe 25, D-33615 Bielefeld, Germany)
  • Received:2006-09-06 Revised:1900-01-01 Published:2007-07-30
  • Contact: CAO Xiao­Ping*

三苯三戊并烯类化合物含三个相互稠合的茚满单元具有独特的刚性骨架, C3v对称性, 凹凸杯状结构. 该类化合物的合成研究具有重要的理论意义和应用前景. 结合自己的研究工作综述了近年来三苯三戊并烯类化合物的合成进展.

关键词: 三苯三戊并烯, 合成, 茚满单元, 杯状分子, 凹凸

Tribenzotriquinacenes are prototypical aromatic hydrocarbon with a particularly rigid, C3v-symmetrical, cup-like convex/concave molecular framework consisting of three mutually fused indane units. In this article the recent progress in the synthesis of tribenzotriquinacene and its derivatives has been reviewed.

Key words: cup-like molecule, indane unit, synthesis, convex/concave structure, tribenzotriquinacene