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有机化学
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有机化学 ›› 2007, Vol. 27 ›› Issue (12): 1463-1472. 上一篇    下一篇

综述与进展

超临界二氧化碳介质中钯催化的一些交叉偶联反应的研究

张涛，冯秀娟*，王春霞，包明*   

  1. (大连理工大学精细化工国家重点实验室 大连 116012)
  • 收稿日期:2006-12-28 修回日期:2007-03-09 发布日期:2007-12-04
  • 通讯作者: 冯秀娟,包明

Cross-Coupling Reactions Catalyzed by Palladium in Supercritical Carbon Dioxide

ZHANG Tao, FENG Xiu-Juan*, WANG Chun-Xia, BAO Ming*   

  1. (State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012)
  • Received:2006-12-28 Revised:2007-03-09 Published:2007-12-04
  • Contact: FENG Xiu-Juan, BAO Ming

PDF

1254

被引次数

3

构建新的C—C键, 在有机合成中占有非常重要的地位; 超临界二氧化碳, 作为环境友好的有机反应介质, 已引起人们的广泛关注. 综述了近年来超临界二氧化碳介质中钯催化的C—C键形成反应的研究进展, 包括Heck, Suzuki, Stille和Sonogashira反应等.

关键词: 超临界二氧化碳, 钯催化, C—C键形成反应

The construction of new carbon-carbon bond is very important in organic synthesis. The supercritical carbon dioxide has attracted considerable attention because it can be used as an environmentally benign medium for organic reactions. In this paper, palladium catalyzed cross-coupling reactions to form new carbon-carbon bond including Heck reaction, Suzuki reaction, Stille reaction as well as Sonogashira reaction, proceeded in supercritical carbon dioxide are reviewed.

Key words: palladium catalysis, carbon-carbon bond formation, supercritical carbon dioxide