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有机化学
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有机化学 ›› 2007, Vol. 27 ›› Issue (9): 1050-1059. 上一篇    下一篇

综述与进展

杂环化合物氮氧化反应研究的新进展

李小童a，庞思平*,b，于永忠a，罗运军a   

  1. (a北京理工大学材料科学与工程学院 北京100081)
    (b北京理工大学生命科学与技术学院 北京100081)
  • 收稿日期:2005-05-23 修回日期:1900-01-01 发布日期:2007-08-30
  • 通讯作者: 庞思平

New Advances in N-Oxidation of Nitrogen-Containing Heterocyclic Compounds

LI Xiao-Tonga,PANG Si-Ping*,b,YU Yong-Zhonga,LUO Yun-Juna   

  1. (a School of Material Science & Engineering, Beijing Institute of Technology, Beijing 100081)
    (b School of Life Science & Technology, Beijing Institute of Technology, Beijing 100081)
  • Received:2005-05-23 Revised:1900-01-01 Published:2007-08-30
  • Contact: PANG Si-Ping

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被引次数

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杂环化合物的N-氧化物是一类重要的有机中间体, 也可以直接用作催化剂、炸药等. 综述了杂环化合物N-氧化反应的最新进展, 包括单氮、双氮和多氮杂环化合物的N-氧化反应, 以及在形成N→O基团的同时合成目标产物的反应, 并重点讨论了具有复杂结构的杂环化合物N-氧化反应.

关键词: 杂环化合物, 结构, N-氧化反应

Heterocyclic N-oxides are important intermediates in organic synthesis and could be used as catalyst and explosive. New advances in N-oxidation nitrogen-containing heterocyclic compounds are reviewed. The reactions include N-oxide reaction of heterocyclic compound with one nitrogen, two nitrogen, or multi nitrogen and the reaction which can provide object product and N→O group at the same time. Especially, the N-oxide reaction of heterocyclic compounds with complicated structure is discussed.

Key words: structure, N-oxidation, heterocyclic compound