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有机化学 ›› 2008, Vol. 28 ›› Issue (05): 910-913. 上一篇    下一篇

研究简报

二-吡啶氧基-轴向取代-四-α-(3-戊氧基)锡(IV)酞菁的合成与表征

彭亦如*,a,b，曹育红a,b，黄风华a,b，翁家宝a,b，黄小霞a,b   

  1. (a福建师范大学化学与材料学院 福州 350007)
    (b中国科学院福建物质结构研究所结构化学国家重点实验室 福州 350003)
  • 收稿日期:2007-08-19 修回日期:2007-10-22 发布日期:2008-05-20
  • 通讯作者: 彭亦如

Synthesis and Characterization of Di(2-pyridyloxy) Axially Substituted Tetra-(α-pentyloxy)tin(IV) Phthalocyanine

PENG Yi-Ru*,a,b,CAO Yu-Honga,b,HUANG Feng-Huaa,b
WEN Jia-Baoa,b,HUANG Xiao-Xiaa,b   

  1. (a College of Chemistry & Materials, Fujian Normal University, Fuzhou 350007)
    (b State Key Laboratory of Structural Chemistry, Chinese Academy of Sci-ence, Fuzhou 350002)
  • Received:2007-08-19 Revised:2007-10-22 Published:2008-05-20
  • Contact: PENG Yi-Ru

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以3-硝基邻苯二甲腈为起始原料, 与正戊醇反应合成3-戊氧基邻苯二甲腈(1), 然后在高温溶剂1-氯萘中经缩聚反应合成二氯-轴向取代-四-α-(3-戊氧基)锡酞菁(2), 2进一步与2-羟基吡啶在N,N-二甲基甲酰胺中合成二-吡啶氧基-轴向取代-四-α-(3-戊氧基)锡酞菁配合物3, 同时对相关化合物分别进行了元素分析, IR, 1H NMR, UV/Vis, 荧光和质谱表征.

关键词: 轴向取代, 锡酞菁, 合成, 表征

3-Pentoxyphthalonitrile (1) was synthesized by using 3-nitrophthalonitrile as raw material. Dichloro-tetra-(α-pentyloxy)tin(IV) phthalocyanine (2) was prepared by condensation of 1 with TiCl4 in 1-chloronaphthalene. A novel axially substituted tin phthalocyanine, namely di(2-pyridyloxy) axially substituted tetra-(α-pentyloxy)tin(IV) phthalocyanine (3) was synthesized by reaction of 2 with 2-hydroxypyridine. The above complexes were characterized by the elemental analysis, UV/Vis, IR, MS, 1H NMR spectra as well as fluorescence spectroscopy.

Key words: tin phthalocyanine, synthesis, characterization, axially substituted