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有机化学
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有机化学 ›› 2008, Vol. 28 ›› Issue (08): 1454-1456. 上一篇    下一篇

研究简报

KF-Al2O3催化下2-氨基-6-甲基-4-芳基-1,3-二氰基苯衍生物的合成

荣良策*,a,b; 韩红霞a ; 蒋 虹b; 庄启亚a ; 王香善a,b ; 屠树江a,b   

  1. (a徐州师范大学化学化工学院 徐州 221116)
    (b江苏省药用植物生物技术重点实验室 徐州 221116)
  • 收稿日期:2007-10-14 修回日期:2008-01-29 发布日期:2008-08-18
  • 通讯作者: 荣良策

Synthesis of 2-Amino-6-methyl-4-aryl-1,3-dicyanobenzene Derivatives Catalyzed by KF-Al2O3

RONG, Liang-Ce*,a,b HAN, Hong-Xiaa JIANG, Hongb ZHUANG, Qi-Yaa
WANG, Xiang-Shana,b TU, Shu-Jianga,b
  

  1. (a College of Chemistry and Chemical Engineering, Xuzhou Normal University, Xuzhou 221116)
    (b The Key Laboratory of Biotechnology for Medical Plants of Jiangsu Province, Xuzhou 221116)
  • Received:2007-10-14 Revised:2008-01-29 Published:2008-08-18
  • Contact: RONG, Liang-Ce

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被引次数

1

以芳醛、丙二腈和丙酮为底物, 乙醇为溶剂, 在70 ℃以KF/Al2O3催化合成了一系列的2-氨基-6-甲基-4-芳基-1,3-二氰基苯衍生物, 产物的结构通过IR, 1H NMR和元素分析确证.

关键词: 苯胺, KF/Al2O3, 合成

A series of 2-amino-6-methyl-4-aryl-1,3-dicyanobenzene derivatives have been synthesized by the reaction of aromatic aldehyde, malononitrile and acetone in EtOH at 70 ℃ catalyzed by KF/Al2O3. The structures of the products were characterized by IR, 1H NMR spectra and elemental analysis.

Key words: KF/Al2O3, synthesis, aniline