有机化学 ›› 2008, Vol. 28 ›› Issue (2): 304-307. 上一篇    下一篇

研究简报

新型萘酰亚胺类衍生物的合成及发光性能的研究

蒋伟a,季俊烽a,王华林a,朱菁b
刘畅b,崔一平b,孙岳明*,a   

  1. (a东南大学化学化工学院 南京 210096)
    (b东南大学电子科学与工程学院 南京 210096)
  • 收稿日期:2007-04-19 修回日期:2007-06-19 发布日期:2008-02-01
  • 通讯作者: 孙岳明

Synthesis of New 1,8-Naphthalimide Derivatives and Their Light Emitting Property

JIANG Weia,JI Jun-Fenga,WANG Hua-Lina,ZHU Jingb
LIU Changb,CUI Yi-Pingb,SUN Yue-Ming*,a   

  1. (a School of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096)
    (b School of Electronic Science and Engineering, Southeast University, Nan-jing 210096)
  • Received:2007-04-19 Revised:2007-06-19 Published:2008-02-01
  • Contact: SUN Yue-Ming

以二芳胺和4-溴-1,8-萘酰亚胺体系为原料, 经CuI/18-crown-6/K2CO3和Pd(OAc)2/P(t-Bu)3/NaOt-Bu两种不同反应催化制备了一系列萘酰亚胺衍生物, 经NMR, MS, 元素分析等表征了其结构, 并用UV-vis和PL (photoluminescence)测定了此类化合物的发光性能.

关键词: 萘酰亚胺, 二芳胺, 丁基磷, 发光性能

三叔The diarylamine reacted with 4-bromo-1,8-naphthalimides to give the new diarylamine-substi- tuted 1,8-naphthalimide derivatives catalyzed by CuI/18-crown-6/K2CO3 or Pd(OAc)2/P(t-Bu)3/NaOt-Bu. The product structures were dem-onstrated by 1H NMR, IR, mass spectra and elemental analysis, and the physical properties were examined by UV-vis and photoluminescence (PL) spectra.

Key words: diarylamine, naphthalimide, tri-tert-butylphosphine, light emitting property