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有机化学
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有机化学 ›› 2009, Vol. 29 ›› Issue (06): 822-834. 上一篇    下一篇

综述与进展

闭式硼烷[B10H10]2－的反应性及其衍生物的应用研究进展

聂 永*,a ; 陈海艳a ; 苗金玲a ; 孙国新a; 窦建民b   

  1. (a济南大学化学化工学院 济南 250022)
    (b聊城大学化学化工学院 聊城 252059)
  • 收稿日期:2008-03-31 修回日期:2008-07-26 发布日期:2009-06-20
  • 通讯作者: 聂 永

Advances in the Chemistry and Applications of the Borane Anion Closo-[B10H10]2－ and Its Derivatives

Nie, Yong*,a; Chen, Haiyana ; Miao, Jinlinga ; Sun, Guoxina; Dou, Jianminb   

  1. (a School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022)
    (b Department of Chemistry, Liaocheng University, Liaocheng 252059)
  • Received:2008-03-31 Revised:2008-07-26 Published:2009-06-20
  • Contact: Nie, Yong

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多面体硼烷化合物以其独特的结构、成键和多方面的潜在应用价值而被广泛研究. 综述了近20年来闭式(closo)硼烷[B10H10]2－的反应性(笼上氢取代、开笼-重排、开笼-金属插入等类型)及其衍生物的应用(硼中子俘获肿瘤治疗、放射性同位素萃取分离、新型材料、超分子化学等方面)研究进展.

关键词: 簇合物, 闭式-, 反应性, 硼烷

In the present paper, the reactivity (hydride substitution, cage opening-rearrangement and cage opening-metal insertion, etc.) of the widely studied closo-borane anion [B10H10]2－ and potential applications (to boron neutron capture therapy of tumors, extraction of radioactive isotopes, new materials and su-pramolecular chemistry, etc.) of its derivatives are reviewed, covering the literature in the past 20 years.

Key words: cluster, closo-[B10H10]2－, reactivi, borane