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有机化学
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有机化学 ›› 2009, Vol. 29 ›› Issue (11): 1799-1803. 上一篇    下一篇

研究论文

新型杯[4]席夫碱的合成及光致变色性质研究

刘志莲*,a,b    张书香a    夏光明a      梁志c      高云华b,c   

  1. (a济南大学化学化工学院 济南 250022) (b中国科学院光化学转换与功能材料重点实验室 北京 100190) (c中国科学院理化技术研究所 北京 100190)
  • 收稿日期:2009-01-15 修回日期:2009-03-30 发布日期:2009-06-19
  • 通讯作者: 刘志莲 E-mail:zhilianliu@163.com
  • 基金资助:

    济南大学博士基金（No.B0637）;国家级.国家自然科学基金

Synthesis and Photochromic Property of Three Novel Calix[4]arene-Schiff Bases

Liu, Zhilian*,a,b      Zhang, Shuxianga           Xia, Guangminga         Liang, Zhic         Gao, Yunhua b,c   

  1. (a College of Chemistry And Chemical Engineering, University of Jinan, Jinan 250022) (b Key Labortory of Photochemical Conversion and Optoelectronic Materials, Chinese Academy of Sciences, Beijing 100190) (c Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190)
  • Received:2009-01-15 Revised:2009-03-30 Published:2009-06-19

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被引次数

17

合成了三种新型含杯[4]芳烃的席夫碱类化合物及不含杯[4]芳烃空腔的模型化合物, 利用IR, 1H NMR, 13C NMR, MALDI-TOF MS和元素分析对其结构进行了表征. 研究了它们的光致变色性能及杯[4]芳烃空腔、取代基和溶剂对光致变色性能的影响. 结果表明, 杯[4]芳烃、取代基OCH3和CH2Cl2可以改善席夫碱的光致变色性能.

关键词: 席夫碱, 杯[4]芳烃, 光致变色, 氢键

Three novel Schiff-bases carrying calix[4]arene and the model compounds without calix[4]arene moieties have been synthesized. The structures of the new compounds were confirmed by IR, 1H NMR, 13C NMR, MALDI-TOF MS and elemental analysis. The calix[4]arene-Schiff bases have photochromic behaviors. Calix[4]arene moieties, substituent OCH3 and solvent CH2Cl2 could effectively improve the photochromic properties of these Schiff-bases.

Key words: Schiff-base, calix[4]arene, photochormism, hydrogen bond