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有机化学
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有机化学 ›› 2010, Vol. 30 ›› Issue (05): 713-718. 上一篇    下一篇

研究论文

3-[2,6-二氯-4-(3,3-二氯烯丙氧基)苯氧基]丙基吡唑-5-羧酸酯类衍生物的合成及杀虫活性

吴同文1，马海军*,2，田辉凯3，倪珏萍2，云志*,1   

  1. (1南京工业大学化学化工学院 南京 210009)
    (2江苏省农药研究所股份有限公司 南京 210019)
    (3南京农业大学植物保护学院 南京 210095)
  • 收稿日期:2009-02-28 修回日期:2009-07-08 发布日期:2009-12-23
  • 通讯作者: 云志 E-mail:yunzhi@njut.edu.cn, zyun99@hotmail.com
  • 基金资助:

    “十一五”国家科技支撑计划(No. 2006BAE01A01-3)资助项目

Synthesis and Insecticidal Activity of 3-[2,6-Dichloro-4- (3,3-dichloroallyloxy)phenoxy]propyl Pyrazole-5- carboxylate Derivatives

Wu Tongwen1 Ma Haijun*,2 Tian Huikai3 Ni Jueping2 Yun Zhi*,1   

  1. (1 College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009)
    (2 Jiangsu Pesticide Research Institute Co., Ltd, Nanjing 210019)
    (3 College of Plant Protection, Nanjing Agricultural University, Nanjing 210095)
  • Received:2009-02-28 Revised:2009-07-08 Published:2009-12-23
  • Contact: YUN Zhi E-mail:yunzhi@njut.edu.cn, zyun99@hotmail.com

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以3-[2,6-二氯-4-(3,3-二氯烯丙氧基)苯氧基]丙醇和5-吡唑甲酸衍生物为原料, 设计并合成了14个未见报道的3-[2,6-二氯-4-(3,3-二氯烯丙氧基)苯氧基]丙基吡唑-5-羧酸酯类衍生物. 目标化合物的结构经IR, 1H NMR和元素分析测定确认. 初步杀虫活性测试结果表明, 该类化合物对鳞翅目害虫具有较好的杀虫活性.

关键词: 二氯烯丙氧基, 吡唑-5-羧酸酯, 合成, 杀虫活性

Fourteen novel 3-[2,6-dichloro-4-(3,3-dichloroallyloxy)phenoxy]propyl pyrazole-5-carboxylate derivatives were synthesized by the reaction of 3-[2,6-dichloro-4-(3,3-dichloroallyloxy)phenoxy]propan-1-ol with pyrazole-5-carboxylic acid derivatives, and confirmed by IR, 1H NMR techniques and elemental analysis. The preliminary bioassay showed that the compounds exhibited good activity against lepidopterous pests.

Key words: dichloroallyloxy, pyrazole-5-carboxylate, synthesis, insecticidal activity