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有机化学
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有机化学 ›› 2010, Vol. 30 ›› Issue (06): 877-883. 上一篇    下一篇

研究论文

微波及超声波辅助合成新型苯环5位Schiff碱取代苯磺酰脲类化合物及除草活性研究

王美怡1，李正名*,2，李永红2   

  1. 1北方民族大学化学与化学工程学院 国家民委化工技术重点实验室 银川 750021)
    (2南开大学元素有机化学研究所 元素有机化学国家重点实验室 天津 300071
  • 收稿日期:2009-09-03 修回日期:2009-12-30 发布日期:2010-02-01
  • 通讯作者: 王美怡 E-mail:ameiwmy2003@163.com
  • 基金资助:

    国家重点基础研究发展计划(No. 2003CB114406)

Microwave and Ultrasound Irradiation-Assisted Synthesis of Novel 5-Schiff Base Substituted Benzenesulfonylurea Compounds

Wang Meiyi1 Li Zhengming*,2 Li Yonghong2   

  1. 1 Key Laboratory for Chemical Engineering and Technology, College of Chemistry and Chemical Engineering, The North University for Ethnics, Yinchuan 750021)
    (2 State Key Labortary of Elemento-organic Chemistry, Research Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071
  • Received:2009-09-03 Revised:2009-12-30 Published:2010-02-01

PDF

865

被引次数

14 | 3

应用微波及超声波等方法辅助, 合成了8个新型Schiff碱取代的磺酰胺, 进而合成出了16个新型磺酰脲化合物. 经1H NMR, MS及元素分析确证了结构, 经油菜平皿法和盆栽法测试了16个磺酰脲化合物的除草活性. 结果表明, 含有Schiff碱取代基的磺酰脲类化合物对双子叶杂草仍然能保持较好的除草活性.

关键词: Schiff碱, 磺酰脲, 合成, 除草活性

8 novel Schiff bases of 5-substituted sulfonamide were synthesized as the intermediates under mild conditions using microwave irradiation or ultrasonic irradiation, and then 16 novel benzenesulfonylurea compounds modified at the 5-position of the benzene ring were synthesized. The structures of all sulfonylurea compounds were confirmed by elemental analysis, MS and 1H NMR techniques. Herbicidal activity of these new sulfonylurea compounds was determined by rape disc and pot bioassay experiments. The result indicated that their herbicidal activity against broadleaf weeds was better than monocotyledonous weeds.

Key words: Schiff base, sulfonylurea, synthesis, herbicidal activity