SIOC English
有机化学
高级检索

有机化学 ›› 2010, Vol. 30 ›› Issue (06): 904-907. 上一篇    下一篇

研究简报

2-苯基-6-肼基-3-哒嗪酮类化合物的合成与表征

景崤壁*，汪清，毕晓昕，吴林韬，颜朝国   

  1. 扬州大学化学化工学院 扬州 225002
  • 收稿日期:2009-09-15 修回日期:2009-11-11 发布日期:2010-01-07
  • 通讯作者: 景崤壁 E-mail:xbjing@yzu.edu.cn

Synthesis and Characterization of 2-Phenyl- 6-hydrazine-3-pyridazione Derivatives

JING Xiao-Bi, WANG Qing, BI Xiao-Xin, WU Lin-Tao, YAN Chao-Guo   

  1. College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002
  • Received:2009-09-15 Revised:2009-11-11 Published:2010-01-07
  • Contact: JING Xiao-Bi E-mail:xbjing@yzu.edu.cn

PDF

1217

被引次数

3 | 1

报道了醚氧乙酰肼类化合物在氢氧化钠存在下可以重排为有机肼类化合物的新方法. 该方法适宜于合成多种取代的2-苯基-6-肼基-3-哒嗪酮类化合物. 产物通过IR, 1H NMR, 13C NMR等方法进行了表征.

关键词: 重排, 哒嗪酮, 哒嗪酮腙, 吡唑

A novel synthetic method for 2-phenyl-6-hydrazine-3-pyridazione derivatives is explored. The key step is the rearrangement of acetyl hydrazine in the existence of NaOH in ethanol to obtain the hydrazine compounds. All their structures were characterized by IR, 1H NMR and 13C NMR spectra.

Key words: rearrangement, pyridazione, pyridazinone hydrazone, pyrazolestructure