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有机化学
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有机化学 ›› 2010, Vol. 30 ›› Issue (08): 1142-1155. 上一篇    下一篇

综述与进展

基于Schiff-Base反应的成环策略及应用

张家强，贾春阳*   

  1. (电子科技大学微电子与固体电子学院 电子薄膜与集成器件国家重点实验室 成都 610054)
  • 收稿日期:2009-08-30 修回日期:2009-12-18 发布日期:2010-02-09
  • 通讯作者: 贾春阳 E-mail:cyjia@uestc.edu.cn
  • 基金资助:

    国家级.国家自然科学基金

Synthetic Strategies and Applications of Macrocycle Molecules Based on Schiff-Base Reaction

 ZHANG  Jia-Qiang, JIA  Chun-Yang   

  1. (State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Microelectronics and Solid-State Electronic, University of Electronic Science and Technology of China, Chengdu 610054)
  • Received:2009-08-30 Revised:2009-12-18 Published:2010-02-09

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被引次数

23 | 3

基于Schiff-base反应的大环化合物是近些年来超分子领域研究的热点. 这些大环化合物不但在传感器、功能材料等领域发挥着重要的作用, 而且在自组装研究领域具有重要的意义. 从模板法和非模板法两方面分析了一些具有代表性Schiff-base大环的合成, 发现, 不但具有合适半径和构型的离子可以作为成环反应的模板, 而且强烈的分子内氢键也能有效地驱动成环反应. 同时, 对于该类大环分子合成所面临的问题及发展方向进行了评述和预测

关键词: 大环化合物, Schiff-base反应, 模板, 氢键

New macrocycle molecules based on Schiff-base reaction have been attracted lots of interest in recent years. These macrocycle molecules play important role not only in the research fields of chemical sensors, functional materials etc., but also in the research field of self-assembly. In this paper, the synthetic strategies of macrocycle molecules will be studied from the results of macrocycle synthesis with templates and without templates. It was found that not only metal ions with suitable diameters and conformations could be as templates for construction of macrocycle molecules, but also the strong intramolecular hydrogen bonds could prompt the formation of macocycle molecules. The problems and development direction of macrocycle molecules based on Schiff-base reaction are also presented.

Key words: macrocycle molecule, schiff-base reaction, template, hydrogen bond