具有表面活性的功能化离子液体N-(三甲氧硅丙基)-N-甲基-2-吡咯烷酮盐酸盐的合成与表征

有机化学 ›› 2011, Vol. 31 ›› Issue (07): 1076-1080. 上一篇下一篇

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具有表面活性的功能化离子液体N-(三甲氧硅丙基)-N-甲基-2-吡咯烷酮盐酸盐的合成与表征

张娇霞^1,2，郑亚萍*^,1，兰岚¹，于培盈¹，石伟¹，李江洪¹，檀雨默¹

(¹西北工业大学理学院应用化学系西安 710129)
(²江苏科技大学材料科学与工程学院镇江 212003)

收稿日期:2010-04-22 修回日期:2011-01-27 发布日期:2011-03-08
通讯作者: 张娇霞 E-mail:myzjx@yahoo.cn

Synthesis and Characterization of Task Specific Ionic Liquid N-(Trimethoxysilyl)propyl-N-methyl-2-pyrrolidone Chlorides with Surface Activities

Zhang Jiaoxia^1,2 Zheng Yaping*^,1 Lan Lan¹ Yu Peiying¹ Shi Wei¹ Li Jiang-hong¹ Tan Yumo¹

(¹ Department of Applied Chemistry, School of Natural and Applied Science, Northwestern Polytechnical University, Xi′an710129)
(²School of Materials Science and En-gineering, Jiangsu University of Science and Technology, Zhenjiang 212003)

Received:2010-04-22 Revised:2011-01-27 Published:2011-03-08
Contact: Jiaoxia Zhang E-mail:myzjx@yahoo.cn

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摘要/Abstract

以N-甲基-2-吡咯烷酮和3-氯丙基三甲氧基硅烷单体为原料, 利用SN2亲核取代反应合成具有一定表面活性的功能化离子液体N-(三甲氧硅丙基)-N-甲基-2-吡咯烷酮盐酸盐. 通过元素分析、红外光谱和核磁共振对功能化离子液体进行表征, 并测定了其表面张力和导电率. 结果表明, 合成的产物结构与其理论结构基本一致, 具有较宽的液体温度范围和较低的表面张力, 并具有较高的电导率, 随着温度的升高, 电导率逐渐增高.

关键词: 功能化离子液体, N-甲基-2-吡咯烷酮, 表面张力, 电导率

A novel task specific ionic liquid with surface activities based on heterocylic pyrrolidone as cation and chloride ion as anion was synthesized using N-methyl-2-pyrrolidone and 3-(trimethoxysilyl) propyl chloride as material through S_N2 nucleophilic substitution reaction. The chemical structure was characterized by elemental analysis, Fourier-transformed infrared spectroscopy (FT-IR) and nuclear magnetic resonance (NMR) analysis. At the same time, the surface-activity and conductivity of task specific ionic liquids were studied. The results showed that the structure of synthesized product is consistent with the theoretical structure of task specific ionic liquids, which has a wide liquid temperature range and low surface tension. The conductivity gradually increased with temperature increasing.

Key words: task specific ionic liquid, N-methyl-2-pyrrolidone, surface tension, conductivity

引用此文

张娇霞, 郑亚萍, 兰岚, 于培盈, 石伟, 李江洪, 檀雨默. 具有表面活性的功能化离子液体N-(三甲氧硅丙基)-N-甲基-2-吡咯烷酮盐酸盐的合成与表征[J]. 有机化学, 2011, 31(07): 1076-1080.

ZHANG Jiao-Xia, ZHENG Ya-Ping, LAN Lan, YU Pei-Ying, SHI Wei, LI Jiang-Hong, TAN Yu-Mo. Synthesis and Characterization of Task Specific Ionic Liquid N-(Trimethoxysilyl)propyl-N-methyl-2-pyrrolidone Chlorides with Surface Activities[J]. Chin. J. Org. Chem., 2011, 31(07): 1076-1080.

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具有表面活性的功能化离子液体N-(三甲氧硅丙基)-N-甲基-2-吡咯烷酮盐酸盐的合成与表征

Synthesis and Characterization of Task Specific Ionic Liquid N-(Trimethoxysilyl)propyl-N-methyl-2-pyrrolidone Chlorides with Surface Activities

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