有机化学 ›› 2011, Vol. 31 ›› Issue (10): 1607-1612. 上一篇    下一篇

研究论文

碱性离子液体[bmim]OH促进一锅串联合成七元硫杂环化合物

娄凤文1,周建峰*,1,林贤福2,陈志春2   

  1. (1淮阴师范学院化学化工学院 江苏省低维材料化学重点建设实验室 淮安 223300)
    (2浙江大学化学系 杭州 310027)
  • 收稿日期:2010-12-30 修回日期:2011-04-11 发布日期:2011-05-03
  • 通讯作者: 周建峰 E-mail:jfchou@126.com

A Facile and Efficient One-Pot Synthesis of Seven-Membered Sulfur Heterocyclic Compounds Using [bmim]OH as Catalyst and Solvent

Lou Fengwen1 Zhou Jianfeng*,1 Lin Xianfu2 Chen Zhichun2   

  1. (1 Jiangsu Province Key Laboratory for Chemistry of Low Dimensional Materials, School of Chemis-try & Chemical Engineering, Huaiyin Normal University, Huaian 223300)
    (2 Department of Chemistry, Zhejiang University, Hangzhou 310027)
  • Received:2010-12-30 Revised:2011-04-11 Published:2011-05-03

(1淮阴师范学院化学化工学院 江苏省低维材料化学重点建设实验室 淮安 223300)
(2浙江大学化学系 杭州 310027)

关键词: [bmim]OH, 硫醇, 丙烯酸乙烯酯, 杂环化合物, 选择性

A rapid method for the straight chain addition of thiols to vinyl acrylates was developed by using basic ionic liquid [bmim]OH as catalyst and solvent. The basic ionic liquid used as catalyst for the cascade reaction of Michael addition and intramolecular addition-elimination reaction in one pot was applied to synthesize a series of sulfur heterocycles bearing lactone or lactam functional groups. In this paper, 18 compounds were synthesized including 12 Michael adducts and 6 sulfur heterocycles. These compounds were characterized by 1H NMR and 13C NMR spectra.

Key words: [bmim]OH, thiol, vinyl acrylate, heterocyclic compound, selectivity

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