有机化学 ›› 2001, Vol. 21 ›› Issue (11): 1029-1039. 上一篇    下一篇

研究论文

金属胶束超分子体系研究新进展

余孝其;向清祥;苏晓渝;游劲松;谢如刚   

  1. 四川大学化学学院.成都(610064)
  • 发布日期:2001-11-25

Reent advances in metalomicellar supramolecular systems

Yu Xiaoqi;Xiang Qingxiang;Su Xiaoyu;You Jinsong;Xie Rugang   

  1. Sichuan Univ, Coll Chem.Chengdu(610064)
  • Published:2001-11-25

综述了近年来金属胶束超分子体系的研究新进展,着重介绍了本科研组应用金属胶束超分子体系模拟羧肽酶A、磷酸酯水解酶、细胞色素P-450等方面的研究成果。并对建立金属胶束超分子体系的动力学处理模型及催化水解反应的机理进行了讨论。

关键词: 金属离子, 羧肽酶, 磷酸酯酶, 细胞色素, 胶束, 金属酶, 模拟酶, 超分子结构

This paper reviews the advances in metallomicellar supramolecular systems in recent years, introduces the research results about the simple chemical models of carboxypeptide A, hydrolase of phosphate and cytochrome- 450 in metallomicellar systems in our research group and discusses the kinetic model of metallomicellar system and the catalytic mechanism.

Key words: METAL ION, CARBOXYL PEPTIDASE, PHOSPHATASE, CYTOCHROME, MICELLE, METALLOENZYME, MODELS OF ENZYME, SUPERMOLECULAR STRUCTURE

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