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有机化学
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有机化学 ›› 2001, Vol. 21 ›› Issue (10): 721-727. 上一篇    下一篇

研究论文

富勒烯的杯芳烃包合物的研究现状与展望

李新红;方鹏飞;陈远荫   

  1. 武汉大学化学与分子科学学院
  • 发布日期:2001-10-25

Researches on the inclusion complex of fullerene and calixarene: current status and prospects

Li Xinhong;Fang Pengfei;Chen Yuanyin   

  • Published:2001-10-25

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865

被引次数

6 | 1

介绍了[60/70]富勒烯与杯[8],[6],[5]芳烃、高氧杂杯[3]芳烃及双杯芳烃形成包合物的研究进展和应用前景。

关键词: 富勒烯, 笼状结构, 杯芳烃, 包合物

Fullerenes have globular structures with external π-electron surfaces, whereas calixarens have cavity structures with internal π- electron surfaces. They could bind to each other by guest-host complexation through π-π interactions. In this paper, an overview of the complexation of fullerenes with various calixarene-based receptors including calix[8] arenes, calix[6] arenes, calix[5] arenes, homooxacalix[3] renes, calix[4] arenes and bridged biscalix[n] arenes along with their preparations, structures, properties and applications is provided.

Key words: FULLERENES, CAGE STRUCTURE, CALIXARENE, CLATHRATES

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