有机化学 ›› 2001, Vol. 21 ›› Issue (10): 713-720. 上一篇    下一篇

研究论文

金属有机化学中的绿色化学反应进展

宋礼成;范洪涛;胡青眉   

  1. 南开大学化学系.天津(300071)
  • 发布日期:2001-10-25

Development of green reactions in organometallic chemistry

Song Licheng;Fan Hongtao;Hu Qingmei   

  1. Nankai Univ, Dept Chem.Tianjin(300071)
  • Published:2001-10-25

着重综述了金属有机化学领域中所涉及的与绿色化学概念有关的一些化学反应,如水相反应、超临界流体及离子液体中的反应、固态反应、原子经济性及过渡金属催化的有机反应。

关键词: 元素有机化学, 有机金属反应, 合成法, 绿色化学

The basic concept and main objectives of green chemistry, especially the organometallic reactions related to green chemistry, are briefly reviewed. The green organometallic reactions covered in this article include solid state reactions, reactions in aqueous media, supercritical fluids and ionic liquids, reactions of high atom economy, and transition metal catalyzed organic reactions. Interestingy, these reactions may lead to give a wide range of organic and organometallic compounds through the enviroment-friendly processes.

Key words: ELEMENTARY ORGANIC CHEMISTRY, ORGANOMETALLIC REACTION, SYNTHESIS METHODS

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