有机化学 ›› 2001, Vol. 21 ›› Issue (9): 690-692. 上一篇    下一篇

研究论文

微波照射下膦酰基/硫甲基烯酮硫代缩醛和N-取代膦酰 基/硫甲基硫代碳酸酯的 合成

陈凯;杨华铮;刘准;胡方中;张春香   

  1. 南开大学元素有机化学研究所.天津(300071);元素有机化学国家重点实验室
  • 发布日期:2001-09-25

Synthesis of novel phosphonyl/s-methyl ketene thioacetals and N- substituted phosphonyl/s-methyl thiocarbonates under microwave irradiation

Chen Kai;Yang Huazheng;Liu Zhun;Hu Fangzhong;Zhang Chunxiang   

  1. Nankai Univ, Elementoorgan Chem Lab.Tianjin(300071)
  • Published:2001-09-25

在微波照射下方便、高收率地合成了新奇的膦酰基杂环的合成子-膦酰基/硫甲基烯酮硫代缩醛和N-取代膦酰基/硫甲基硫代碳酸酯,实验表明微波照射大大加快了反应速率和提高了反应产率。

关键词: 微波辐射, 烯酮P, 硫代, 缩醛, 硫甲基, 硫代碳酸, 磷杂环化合物, 有机磷化合物, 碳酸酯, 磷酰化合物, 合成子, 合成

Phosphonyl/S-methyl ketene thioacetals and N-substituted phosphonyl/S-methyl thiocarbonates-novel kinds of synthons for the synthesis of phosphonyl heterocyclic compounds were conveniently synthesized under microwave irradiation with high yields. It showed that the reaction process was significantly enhanced using microwave heating.

Key words: MICROWAVE RADIATION, KENONE P, THIA-, ACETAL, CARBONO THIOIC ACID, PHOSPHOROUS HETEROCYCLIC COMPOUNDS, ORGANO PHOSPHORUS COMPOUNDS, POLYCARBONATE, PHOSPHORYL COMPOUNDS, SYNTHESIS

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