有机化学 ›› 2003, Vol. 23 ›› Issue (4): 313-320. 上一篇    下一篇

研究论文

过渡金属催化的炔烃芳构化反应

程金生;江焕峰;张群健;欧阳小月   

  1. 中国科学院广州化学研究所
  • 发布日期:2003-04-25

Transiton Metal Catalyzde Aromatization of Alkynes

Cheng JinSheng;Jiang HuanFeng;Zhang QunJian;OuYang XiaoYue   

  1. Laboratory of Cellulose and Lignocellulosics Chemistry, Guangzhou Institute of Chemistry,Chinese Academy of sf Scidnces
  • Published:2003-04-25

综述了过渡金属催化的炔烃环三聚芳构化反应的历史沿革及最新研究进展,并 重点对含有不同电性取代基的炔烃环三聚反应、几种典型的催化体系和作用机理、 该领域的一些前沿热点作了评述.

关键词: 过渡金属络合物, 炔烃, 芳构化, 三聚物, 反应机理

The recent progress in transition metal catalyzed cyclotrimerization aromatization of alkynes is reviewed in this paper, with particular attention directed to the cyclotrimerization reactions of alkynes containing different electrical characteristic substituents, some typical catalyst systems, the reaction mechanisms, and some hotspots in this area.

Key words: TRANSITION METAL COMPLEX;ALKYNE;AROMATIZATION;trimer, REACTION MECHANISM

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