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有机化学
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有机化学 ›› 2009, Vol. 29 ›› Issue (06): 858-866. 上一篇    下一篇

综述与进展

含卤素取代基四硫富瓦烯的合成与研究进展

李洪启*,a ; 宋燕西b ; 李秀梅c   

  1. (a东华大学化学化工与生物工程学院 上海 201620)
    (b东华大学环境科学与工程学院 上海 201620)
    (c内蒙古通辽职业学院理工系 通辽 028000)
  • 收稿日期:2008-01-25 修回日期:2008-10-14 发布日期:2009-06-20
  • 通讯作者: 李洪启

Advances in Synthesis and Research of Tetrathiafulvalenes Containing Halogen Substituent

Li, Hongqi*,a; Song, Yanxib ; Li, Xiumeic   

  1. (a College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620)
    (b College of Environmental Science and Engineering, Donghua University, Shanghai 201620)
    (c Department of Physics and Technology, Inner Mongolia Tongliao Vocational College, Tongliao 028000)

  • Received:2008-01-25 Revised:2008-10-14 Published:2009-06-20
  • Contact: Li, Hongqi

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被引次数

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简要概括了含卤素取代基四硫富瓦烯(TTF)衍生物的主要合成方法, 即TTF及其衍生物的直接卤化法以及卤代1,3-二硫杂环戊烯-2-(硫)酮在亚磷酸三烷基酯参与下的偶合反应. 介绍了含卤素TTF衍生物的电化学、结晶和成膜性能, 及其作为重要的合成中间体在构筑给体-受体二元体、低聚TTF体系、含TTF单元的环蕃、含TTF单元的聚合物以及各种官能化TTF衍生物中的应用. 提出了含卤素TTF衍生物的研究发展趋势.

关键词: 卤素取代基, 合成中间体, 合成, 电化学性能, 四硫富瓦烯

The two main methods for the synthesis of tetrathiafulvalene (TTF) derivatives containing halogen substituent, namely the direct halogenation of TTF and its derivatives and the trialkyl phosphite-mediated coupling of halogenated 1,3-dithiole-2-thione (or 2-one) compounds are outlined briefly. Electrochemical, crystalline, and film-forming properties as well as applications to construction of donor-acceptor dyads, oli-gomeric TTF systems, TTF-containing cyclophanes, TTF-containing polymers, and other functionalized TTF systems are reviewed. The development trends in research on TTF derivatives containing halogen substituent are proposed.

Key words: halogen substituent, synthetic intermediate, synthesis, electrochemical property, tetrathiafulvalene