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有机化学
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有机化学 ›› 2009, Vol. 29 ›› Issue (9): 1434-1439. 上一篇    下一篇

研究简报

新型光敏剂——系列尾式卟啉二肽的合成与光学性质研究

罗国添*,a,b 徐庆兵a 陈治希a 滕莉丽a   

  1. (a赣南师范学院化学与生命科学学院 赣州 341000)
    (b江西省有机药物化学重点实验室 赣州 341000)
  • 收稿日期:2008-11-19 修回日期:2009-01-24 发布日期:2009-12-30
  • 通讯作者: 罗国添

Synthesis and Optical Properties of a Series of New Tailed Porphyrinate Dipeptide

Luo, Guotian *,a,b Xu, Qingbing a Chen, Zhixi a Teng, Lili a   

  1. (a College of Chemistry and Life Science, Gannan Normal University, Ganzhou 341000)
    (b Key Laboratory of Organo-Pharmaceutical Chemistry, Jiangxi Province, Ganzhou 341000)
  • Received:2008-11-19 Revised:2009-01-24 Published:2009-12-30
  • Contact: Luo, Guotian

PDF

2228

被引次数

16 | 4

以5-(4-氨基苯基)-10,15,20-三苯基卟啉、叔丁氧羰基(Boc)保护的氨基酸为原料合成了系列新型尾式氨基酸卟啉和尾式卟啉二肽, 用核磁、质谱及元素分析对产物进行了表征, 并研究了其光学性质. 结果表明: 所合成的系列尾式卟啉二肽产率高达94%以上, 在可见光的红光部分有强烈的荧光发射.

关键词: 尾式卟啉二肽, 合成, 光学性质

A series of new tailed porphyrinate dipeptides were designed and synthesized by the reactions of 5-(4-aminophenyl)-10,15,20-triphenylporphyrin with Boc protected amino acid. The target products and in-termediates were characterized by MS, 1H NMR techniques and elemental analysis, and their optical proper-ties were researched. The yields were up to 94%. The tailed porphyrinate dipeptides have strong fluores-cence emission in the red region of the spectrum.

Key words: synthesis, optical property, tailed porphyrinate dipeptide