关键词: 生物活性, 拟除虫菊素杀虫剂, 除虫菊素, 环丙烷 P, 苯甲醇 P, 环丙甲酸 P, 有机氟化合物, 消旋体拆分, 有机氯杀虫剂, 构型, 丙烯基, 有机氟杀虫剂

The synthesis of the title acid as well as p-MeOCH2C6H4CHROH (R = H, CYCH) and p-MeOCH2C6H4CHO are reported. The (+)-cis and (-)-cis acids were obtained by resoln. of the (?-cis-acids. (?-Cis, (+)-cis, (-)-cis acids were esterified with the alcs. and the aldehyde to give esters I (R = H, cyano, CYCH). To establish the influence of the absolute configuration at the chiral centers of the acid on the biol. activity of I, the activity of the esters were tested. The results showed that the (+)-cis isomer exhibited the highest activity.

Key words: BIOLOGICAL ACTIVITY, SYNTHETIC PYRETHROID-INSECTICIDES, PYRETHRINS, CYCLOPROPANE P, BENZALCOHOL P, CYCLOPROPANE CARBOXYLIC ACID P, ORGANO FLUORINE COMPOUNDS, MESOTOMY, ORGANOCHLORINE INSECTICIDES, CONFIGURATION, PROPENYL GROUP, ORGANOFLUORINE INSECTICIDES