有机化学 ›› 1990, Vol. 10 ›› Issue (3): 277-281. 上一篇    下一篇

研究论文

中国南海软珊瑚Sinularia microclavate 化学成份的研究

刘铸晋;李健雄;吴厚铭   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1990-06-25

A study on chemical constituents of south china sea soft coral sinularia microclavate

LIU ZHUJIN;LI JIANXIONG;WU HOUMING   

  • Published:1990-06-25

本文报导, 中国南海小棒短指软珊瑚的乙醇提取物经分配, 柱层析高压液相层析和气相层析等手段分离纯化得到11个化合物, 为弄清它的生理活性的起源, 本文对它的化学成份进行了研究。

关键词: 紫外分光光度法, 海洋生物, 十六碳化合物, 质子磁共振谱法, 红外分光光度法, 胆甾醇, 质谱法, 羧酸酯, 十四碳化合物, 喹啉酮 P

The chem. constituents of South China Sea soft coral S. microclavate were studied. A series of fatty compounds including octadecyl palmitate, Et myristate, Et palmitate, Et stearate, octadecyl alcohol, hexadecyl alcohol, and a common steroid, ergosta-5,24(28)-diene-3-ol were isolated. In addition 2 alkyl glycerin monoethers containing a C 15 and C 17 alkyl group, resp., and a rarely found compound, N-phenyl-b-naphthylamine were isolated from soft coral for the first time. Finally, 7-hydroxy-8-methoxy-4(1H)-quinolone was identified as the bioactive constituent. All the structures of these constituents were characterized on the basis of their spectral data together with their chem. behaviors.

Key words: C16 COMPOUNDS, ULTRAVIOLET SPECTROPHOTOMETRY, INFRARED SPECTROPHOTOMETRY, MARINE ORGANISMS, PROTON MAGNETIC RESONANCE SPECTROMETRY, CHOLESTEROL, MASS SPECTROGRAPHY, C14 COMPOUNDS, CARBOXYLIC ACID ESTER, QUINOLINONE P

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