有机化学 ›› 1990, Vol. 10 ›› Issue (6): 525-528. 上一篇    下一篇

研究论文

某些新的含醛基和二氰基乙烯基的偶氮染料的合成和可见光谱

阮明德;范伟强;陈旭光   

  1. 杭州大学化学系;浙江省冶金研究所
  • 发布日期:1990-12-25

The synthesis and visible spectra of some novel azo dyes containing aldehyde and dicyanomethylidene groups

RUAN MINGDE;FAN WEIQIANG;CHEN XUGUANG   

  • Published:1990-12-25

本工作合成了一系列新含醛基的偶氮染料, 并将-CHO转变为-CH=C(CN)2, 然后测定了这些染料在各种介质中的可见光谱, 以考察二氰基乙烯基对偶氮染料的红移作用及酸碱介质的影响。

关键词: 丙二腈 P, 醛, 红外分光光度法, 元素分析, 质子磁共振谱法, 乙烯 P, 偶氮染料, 红移

Reaction of p-diazobenzaldehyde hydrogen sulfate with PhNH2, PhOH, naphthylamine, and naphthol derivatives gave azo dyes containing conjugated aromatic aldehyde groups. Condensation of the aldehyde-contg. azo dyes with malonitrile gave dicyanomethylidene-contg. azo dyes and caused bathochromic shifts in the UV spectra. The dyes containing amino groups caused red shifts in acid solvents and those containing hydroxy groups caused red shifts in basic solvents.

Key words: INFRARED SPECTROPHOTOMETRY, PROPANEDINITRILE P, ELEMENTAL ANALYSIS, ALDEHYDES, PROTON MAGNETIC RESONANCE SPECTROMETRY, ETHYLENE P, AZO DYES, RED SHIFT

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