有机化学 ›› 1991, Vol. 11 ›› Issue (2): 195-198. 上一篇    下一篇

研究论文

金属锡作用下炔丙基碘与醛类化合物的反应

邵秋宜;高翔;孙培冬;吴世晖   

  1. 复旦大学化学系
  • 发布日期:1991-04-25

Reaction of propargyl idodide with aldehydes in the presence of metallic tin

SHAO QIUYI;GAO XIANG;SUN PEIDONG;WU SHIHUI   

  • Published:1991-04-25

本文首次报道金属锡作用下的炔丙基碘与醛类化合物的反应。

关键词: 红外分光光度法, 丙炔 P, 锡, 质子磁共振谱法, 碘代烃,

In the presence of metallic tin, propargyl iodide reacted with RCHO (R = Ph, substituted Ph, PhCH:CH) in dry THF to give a mixture of RCH(OH)CH2CYCH, and RCH(OH)CH:C:CH2 in good yield.

Key words: TIN, INFRARED SPECTROPHOTOMETRY, PROTON MAGNETIC RESONANCE SPECTROMETRY, PROPYNE P, IODOHYDROCARBON, ALDEHYDES

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